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CuI and CuII Salts of Group VIA Elements as Catalysts for Living Radical Polymerization Initiated with Sulfonyl Chlorides - Published online 5 September 2000 - A new class of nonacidic Cu2Y/Bpy and CuY/Bpy catalysts (where Y is O, S, Se, or Te and Bpy is 2,2'-bipyridine) for the living radical polymerization of vinylic monomers initiated from sulfonyl halides is described. A polymerization mechanism based on the in situ generation of the CuCl/CuCl2 pair is suggested. The experimental rate constants of polymerization were higher for the Cu2Y-based catalysts and increased for both the Cu2Y and CuY catalysts in the order Y = O < S < Se < Te./
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| No. | 권호·제본정보 보기 | 소장처 | 소장사항 | 청구기호 | 구독 | 최근입수호 |
|---|---|---|---|---|---|---|
| 1 | 중앙도서관/3층 연속간행물(보존)/ | 547 J86A | 구독중 | Vol.45 No.16 | ||
| 2 | 중앙도서관/3층 연속간행물실/ | 547 J86A | 구독중 | Vol.45 No.24 |
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