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RAPID COMMUNICATION - Syntheses of Stimuli-Responsive Block Copolymers of Vinyl Ethers with Side Oxyethylene Groups by Living Cationic Polymerization and Their Thermosensitive Physical Gelation - Published online 19 September 2000 Diblock copolymers of vinyl ethers with oxyethylene pendants were synthesized by living cationic polymerization in the presence of an added base. The characteristic physical gelation behavior was examined by varying the temperature of aqueous polymer solutions. When the solution was allowed to warm, physical gelation occurred quite sensitively in a limited temperature region, maintaining transparency./
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