Mono(cyclopentadienyl) and ansa-bis-(cyclopentadienyl)imido derivatives of Group 5 and 6 transition metals; crystal structures of [M{(eta-C~5H~4)CMe~2(eta-C~5H~4)}(NR)X] (M = Nb, R = SiMe~3, X = Cl; R = Bu^t, X = Cl, Br or I; M = Ta, R = Bu^t,X = Cl)