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Crystal structures and spectral properties of five-coordinate copper(II)complexes with N,N,N',N",N"-pentamethyldiethylenetriamine (pmdt) and �diamines: approximately regular trigonal bipyramidal [Cu(en)(pmdt)](ClO~4)~2 and highly distorted [Cu(SS-chxn)(pmdt)](ClO~4)~2 (en = 1,2-diaminoethane and SS-chxn = (1S,2S)-1,2-diaminocyclohexane)
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