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Evolution of Molecular Weight Distributions in the Catalytic Chain Transfer Polymerization of Methyl Methacrylate up to High Monomer Conversions - The evolution of molecular weight distributions (MWDs) with monomer conversion in the catalytic chain transfer (CCT) polymerization of methyl methacrylate at 60 (degree)C is investigated by simulation (via the program package PREDICI(R)) and experiment. The small shifts seen in the MWD toward lower molecular weights with increasing monomer conversion are shown to be of the same order of magnitude as the associated changes in the MWD in non-CCT controlled free-radical polymerization, indicating that no significant change in the MWD with monomer conversion is associated with the CCT process/
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