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Synthesis of Photocrosslinkable Fluorinated Polydimethylsiloxanes: Direct Introduction of Acrylic Pendant Groups via Hydrosilylation - Published online 28 August 2000 - The synthesis of photocrosslinkable fluorinated polydimethylsiloxanes was achieved in two steps through direct hydrosilylation between copoly(dimethyl)(methyl-hydrogen) siloxane, first with a fluorinated olefin and then with allyl methyl methacrylate. The products were characterized by IR, 1H NMR, 19F NMR, and 29Si NMR. The photocrosslinked polymer may find application as a vapor permeation membrane./
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