부가기능
Self-Polyaddition of Hydroxyalkyl Vinyl Ethers - Published online 30 August 2000 - The hydroxyalkyl vinyl ethers 2-hydroxyethyl vinyl ether, 4-hydroxybutyl vinyl ether, and 6-hydroxyhexyl vinyl ether were polymerized in tetrahydrofuran in the presence of pyridium p-toluenesulfonate as a catalyst. The polymerization proceeded by a step-growth self-polyaddition mechanism (route 2) rather than a cationic chain-reaction process (route 1). The resulting polymers possessed a polyacetal main chain instead of a carbon-carbon backbone. The copolymerization of two monomers also proceeded smoothly, generating the corresponding acetal copolymers./
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