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Pendent Polymers of 1-Methyl-2-Oxo-4,5-Dicyanoimidazole and Their Electrochemical Properties - Published online 7 September 2000 - The electron-accepting 1-methyl-4,5-dicyanoimidazole group was attached to vinyl polymers, via an alkoxy link, by nucleophilic aromatic substitution (NAS) of 1-methyl-2-fluoro-4,5-dicyanoimidazole (1). The cyclic voltammetry (CV) studies show that monomeric and oligomeric model compounds are electrochemically quasi-reversible, and the degree of reversibility decreases as dicyanoimidazoles become more proximate within a molecule./
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