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Fluorocarbon-Ended Polymers: Metal Catalyzed Radical and Living Radical Polymerizations Initiated by Perfluoroalkylsulfonyl Halides - Perfluoroalkylsulfonyl halides initiate the metal catalyzed living radical polymerization of styrene and methyl methacrylate with loss of SO2. Both polymers contain perfluoroalkyl chain ends. The radical copolymerization of tetrafluoroethylene with hexafluoropropylene initiated with perfluoroalkylsulfonyl halides in catalyzed by both metal halides and metal zero from the reactor walls/
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